222380

Allylpalladium(II) chloride dimer

98%

• 동의어(들): Bis((η3-allyl)(chloro)palladium), Di-ο-allyldi-μ-chlorodipalladium, [PdCl(C₃H₅)]₂
• 실험식(Hill 표기법): C₆H₁₀Cl₂Pd₂
• CAS Number: 12012-95-2
• Molecular Weight: 365.89
• Beilstein: 4124623
• EC Number: 234-579-8
• MDL number: MFCD00044874
• UNSPSC 코드: 12161600
• PubChem Substance ID: 24853328
• NACRES: NA.22

속성

• Quality Level: 200
• 분석: 98%
• 형태: solid
• 반응 적합성: core: palladium; reaction type: Cross Couplings; reagent type: catalyst; reaction type: C-H Activation
• 환경친화적 대안 제품 특성: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• 환경친화적 대안 카테고리: , Aligned
• 저장 온도: 2-8°C
• SMILES string: Cl[Pd]CC=C.Cl[Pd]CC=C
• InChI: 1S/2C3H5.2ClH.2Pd/c2*1-3-2;;;;/h2*3H,1-2H2;2*1H;;/q;;;;2*+1/p-2
• InChI key: TWKVUTXHANJYGH-UHFFFAOYSA-L

설명

일반 설명

Allylpalladium(II) chloride dimer is employed as catalyst in Heck reaction. It also participates as catalyst in the tandem nucleophilic allylation-alkoxyallylation reaction of the alkynylaldehydes with allyl chloride and allyltributylstannane.

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

애플리케이션

Application Guide for Palladium Catalyzed Cross-Coupling Reactions

Allylpalladium(II) chloride dimer has been employed for the following studies:

• Synthesis of cationic palladium cataysts, used in the microwave-assisted Heck arylation.
• Synthesis of N-heterocyclic carbene-palladium-η³-allyl chloride complexes, which are efficient catalyst for the Suzuki-Miyaura cross-coupling of aryl bromides and activated aryl chlorides.
• Synthesis of 1,4-diallyl-1,2-dihydroisoquinolines.
• As catalyst for greener Buchwald-Hartwig coupling in TPGS-750-M.

On the Way Towards Greener Transition-Metal-Catalyzed Processes as Quantified by E Factors

안전성 정보

• 픽토그램: GHS07
• 신호어: Warning
• 유해 및 위험 성명서: H315
• 예방조치 성명서: P264 - P280 - P302 + P352 - P332 + P313 - P362 + P364
• Hazard Classifications: Skin Irrit. 2
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• 개인 보호 장비: dust mask type N95 (US), Eyeshields, Faceshields, Gloves