75920

OXONE^® tetrabutylammonium salt

technical, ~1.6% active oxygen basis

• 동의어(들): Tetrabutylammonium OXONE^®, Tetrabutylammonium hydrogen monopersulfate, Tetrabutylammonium peroxomonosulfate, Tetrabutylammonium persulfate triple salt
• CAS Number: 104548-30-3
• Beilstein: 5199887
• UNSPSC 코드: 12352000
• PubChem Substance ID: 24886893
• NACRES: NA.22

속성

• Quality Level: 100
• grade: technical
• 형태: powder
• 반응 적합성: reagent type: oxidant
• 농도: ~1.6% (active oxygen)
• mp: 144-146 °C
• SMILES string: OS([O-])(=O)=O.[O-]S([O-])(=O)=O.OS(=O)(=O)O[O-].OS(=O)(=O)O[O-].CCCC[N+](CCCC)(CCCC)CCCC.CCCC[N+](CCCC)(CCCC)CCCC.CCCC[N+](CCCC)(CCCC)CCCC.CCCC[N+](CCCC)(CCCC)CCCC.CCCC[N+](CCCC)(CCCC)CCCC
• InChI: 1S/5C16H36N.2H2O5S.2H2O4S/c5*1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;2*1-5-6(2,3)4;2*1-5(2,3)4/h5*5-16H2,1-4H3;2*1H,(H,2,3,4);2*(H2,1,2,3,4)/q5*+1;;;;/p-5
• InChI key: IGMBKNUVZFAHJM-UHFFFAOYSA-I

설명

애플리케이션

Reagent for:

• Oxidation of Hantzsch 1,4-Dihydropyridines catalyzed by manganese(III) Schiff Base complexes
• Epoxidation of alkenes
• Oxidation of sulfides and olefins
• Oxidation of alcohols
• Oxidation of aromatic amines for synthesis of azoxy arenes

기타 정보

Form of Oxone specially suited for the oxidation of sensitive compounds in CH₂Cl₂; Reagent for preparing 2-tetrahydrofuranyl ethers from alcohols and THF by radical coupling

법적 정보

OXONE is a registered trademark of E. I. du Pont de Nemours and Company

안전성 정보

• 픽토그램: GHS05,GHS07
• 신호어: Danger
• 유해 및 위험 성명서: H302,H314
• 예방조치 성명서: P260 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Oral - Skin Corr. 1B
• Storage Class Code: 8A - Combustible corrosive hazardous materials
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• 개인 보호 장비: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges