추천 제품
Grade
for GC derivatization
분석
≥98.0% (GC)
형태
liquid
품질
LiChropur™
반응 적합성
reagent type: derivatization reagent
reaction type: Silylations
기술
gas chromatography (GC): suitable
refractive index
n20/D 1.402 (lit.)
bp
172-175 °C (lit.)
density
1.036 g/mL at 25 °C (lit.)
저장 온도
2-8°C
SMILES string
CN(C(=O)C(F)(F)F)[Si](C)(C)C(C)(C)C
InChI
1S/C9H18F3NOSi/c1-8(2,3)15(5,6)13(4)7(14)9(10,11)12/h1-6H3
InChI key
QRKUHYFDBWGLHJ-UHFFFAOYSA-N
유사한 제품을 찾으십니까? 방문 제품 비교 안내
일반 설명
N-tert-Butyldimethylsilyl-N-methyltrifluoroacetamide is a silylating reagent which replaces the active hydrogen with tert-Butyldimethylsilyl group. The tert-Butyldimethylsilyl derivatives are found to be more resistant to hydrolysis and stable compared to trimethylsilyl (TMS) derivatives. This reagent is suitable for GC-MS analysis since it produces mass spectra, which can be easily interpreted. It is widely used for the silylation of different alcohols, thiols, phenols, carboxylic acids, amines, and amides.
애플리케이션
N-tert-Butyldimethylsilyl-N-methyltrifluoroacetamide may be used as a derivatizing reagent for the determination of methionine sulfoxide and methionine in blood plasma and chlorpyrifos, diazinon and their major metabolites in sludge and sludge-fertilized agricultural soils using gas-chromatography coupled to mass spectrometry technique.
법적 정보
LiChropur is a trademark of Merck KGaA, Darmstadt, Germany
관련 제품
제품 번호
설명
가격
신호어
Warning
유해 및 위험 성명서
Hazard Classifications
Flam. Liq. 3
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point (°F)
113.0 °F - closed cup
Flash Point (°C)
45 °C - closed cup
이미 열람한 고객
Advanced Gas Chromatography: Progress in Agricultural, Biomedical and Industrial Applications (2012)
Highly selective sample preparation and gas chromatographic?mass spectrometric analysis of chlorpyrifos, diazinon and their major metabolites in sludge and sludge-fertilized agricultural soils
Journal of Chromatography A, 1132(1-2), 21-27 (2006)
Two stage derivatization with N-(tert.-butyldimethylsilyl)-N-methyl-trifluoroacetamide (MTBSTFA) and N-methyl-bis-(trifluoroacetamide)(MBTFA) for the gas-chromatographic analysis of OH-, SH-and NH-compounds
Fresenius Journal of Analytical Chemistry, 348(5-6), 364-370 (1994)
Analytical biochemistry, 313(1), 28-33 (2003-02-11)
Methionine sulfoxide is an oxidation product of methionine with reactive oxygen species via 2-electron-dependent mechanism. Such oxidants can be generated from activated neutrophils; therefore, methionine sulfoxide can be regarded as a biomarker of oxidative stress in vivo. We describe here
문서
Results of a study involving the ability few Fluka silylating reagents to form GC-MS-compatible trimethylsilylmethyl derivatives of NSAIDs
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