362824

アセチルトリメチルシラン

97%

• 別名: 1-(トリメチルシリル)エタノン
• 化学式: (CH₃)₃SiCOCH₃
• CAS番号: 13411-48-8
• 分子量: 116.23
• Beilstein: 2071361
• MDL番号: MFCD00134244
• UNSPSCコード: 12352103
• PubChem Substance ID: 24862334
• NACRES: NA.22

特性

• 品質水準: 100
• アッセイ: 97%
• 屈折率: n20/D 1.411 (lit.)
• 密度: 0.811 g/mL at 25 °C (lit.)
• 保管温度: 2-8°C
• SMILES記法: CC(=O)[Si](C)(C)C
• InChI: 1S/C5H12OSi/c1-5(6)7(2,3)4/h1-4H3
• InChI Key: REDWSDBFBCDPNI-UHFFFAOYSA-N

詳細

詳細

Acetyltrimethylsilane is an organosilicon compound that is commonly used as a protective agent for alcohols and amines in organic synthesis. It is also used as a reagent in various reactions, which includes trimethylsilylation, condensation, carbon-carbon bond formation, and reductive amination reactions.

アプリケーション

Acetyltrimethylsilane can be used as a reagent in the synthesis of dihydrophenanthrenes via a C-C insertion reaction. It is also used as a source of carbanion in the synthesis of unsymmetrical biaryls by carbanion-induced ring transformation of 2H-pyran-2-ones under mild basic conditions.

安全性情報

• ピクトグラム: GHS02,GHS07
• シグナルワード: Danger
• 危険有害性情報: H225,H315,H319,H335
• 注意書き: P210 - P302 + P352 - P305 + P351 + P338
• 危険有害性の分類: Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
• ターゲットの組織: Respiratory system
• 保管分類コード: 3 - Flammable liquids
• WGK: WGK 3
• 引火点(°F): 46.4 °F - closed cup
• 引火点(℃): 8 °C - closed cup
• 個人用保護具 (PPE): Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter