525685

Bis(hexylene glycolato)diboron

96%

• 実験式（ヒル表記法）: C₁₂H₂₄B₂O₄
• CAS番号: 230299-21-5
• 分子量: 253.94
• MDL番号: MFCD06246008
• UNSPSCコード: 12352103
• PubChem Substance ID: 24874501
• NACRES: NA.22

特性

• 品質水準: 100
• アッセイ: 96%
• mp: 98-102 °C (lit.)
• SMILES記法: CC1CC(C)(C)OB(O1)B2OC(C)CC(C)(C)O2
• InChI: 1S/C12H24B2O4/c1-9-7-11(3,4)17-13(15-9)14-16-10(2)8-12(5,6)18-14/h9-10H,7-8H2,1-6H3
• InChI Key: UEBSWKNVDRJVHN-UHFFFAOYSA-N

詳細

アプリケーション

Bis(hexylene glycolato)diboron can be used as a reagent:

• To prepare aryl boronate esters via metal-catalyzed direct C-H borylation of aryl compounds.
• In the chemoselective synthesis of C−C coupling products via nickel catalyzed coupling of primary and secondary alkyl halides.
• In the nickel-catalyzed regioselective arylboration of terminal nonactivated alkenes to yield alkyl boranes.

安全性情報

• 保管分類コード: 11 - Combustible Solids
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable
• 個人用保護具 (PPE): Eyeshields, Gloves, type N95 (US)