709492

(1S,4S,8S)--5-ベンジル-8-メトキシ-1,8-ジメチル-2-(2'-メチルプロピル)-ビシクロ[2.2.2]オクタ-2,5-ジエン

97%

• 別名: (1S,4S,8S)-5-ベンジル-2-イソブチル-8-メトキシ-1,8-ジメチル-2-ビシクロ[2.2.2]オクタ-2,5-ジエン, (1S,4S,8S)-5-ベンジル-2-イソブチル-8-メトキシ-1,8-ジメチルビシクロ[2.2.2]オクタ-2,5-ジエン, (1S,4S,8S)Carreira DOLEFIN 配位子
• 実験式（ヒル表記法）: C₂₂H₃₀O
• CAS番号: 862499-50-1
• 分子量: 310.47
• MDL番号: MFCD09265063
• UNSPSCコード: 12352112
• PubChem Substance ID: 329762875
• NACRES: NA.06

特性

• 品質水準: 100
• アッセイ: 97%
• フォーム: liquid
• 光学活性: [α]/D −84±5°, c = 0.5 in chloroform
• 反応適合性: reaction type: click chemistry
• 屈折率: n20/D 1.522
• 官能基: ether; phenyl
• SMILES記法: CO[C@@]1(C)C[C@@]2(C)C=C(Cc3ccccc3)[C@@H]1C=C2CC(C)C
• InChI: 1S/C22H30O/c1-16(2)11-19-13-20-18(12-17-9-7-6-8-10-17)14-21(19,3)15-22(20,4)23-5/h6-10,13-14,16,20H,11-12,15H2,1-5H3/t20-,21+,22-/m0/s1
• InChI Key: ACWLDJOHMGJACE-BDTNDASRSA-N

詳細

詳細

(1S,4S,8S)-5-Benzyl-2-isobutyl-8-methoxy-1,8-dimethylbicyclo[2.2.2]octa-2,5-diene, an enantiopure diene ligand developed by Carreira, is most commonly used in asymmetric catalysis. It is generally prepared from commercially available (R)-carvone.

アプリケーション

Carreira DOLEFIN Ligands

(1S,4S,8S)-5-Benzyl-2-isobutyl-8-methoxy-1,8-dimethylbicyclo[2.2.2]octa-2,5-diene is mainly useful for the stereoselective synthesis of diarylmethine stereogenic centers.

安全性情報

• 保管分類コード: 10 - Combustible liquids
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable