795569

Garg 4,5-indolyne precursor

95%

• 別名: 4-(Trimethylsilyl)-1H-indol-5-yl trifluoromethanesulfonate
• 実験式（ヒル表記法）: C₁₂H₁₄F₃NO₃SSi
• CAS番号: 1259448-37-7
• 分子量: 337.39
• MDL番号: MFCD25976536
• UNSPSCコード: 12352100
• PubChem Substance ID: 329768491
• NACRES: NA.22

特性

• 品質水準: 100
• アッセイ: 95%
• 形状: solid
• mp: 43-48 °C
• 官能基: fluoro; triflate
• 保管温度: 2-8°C
• SMILES記法: O=S(OC1=C([Si](C)(C)C)C2=C(NC=C2)C=C1)(C(F)(F)F)=O
• InChI: 1S/C12H14F3NO3SSi/c1-21(2,3)11-8-6-7-16-9(8)4-5-10(11)19-20(17,18)12(13,14)15/h4-7,16H,1-3H3
• InChI Key: LLCJFYYASDIOJN-UHFFFAOYSA-N

詳細

詳細

Garg 4,5-indolyne precursor is an indolyne precursor developed by Professor Neil Garg and coworkers. It is widely used for the synthesis of various N-heterocyclic based compounds. It is also useful for the preparation of substituted indoles (Diels–Alder and azide cycloaddition products).

アプリケーション

Indolyne precursor can be activated under mild fluoride conditions, which are highly reactive with dienes and other dipolariphiles (e.g. azides) to provide cycloaddition products containing an indole motif.

その他情報

Indolyne Experimental and Computational Studies: Synthetic Applications and Origins of Selectivities of Nucleophilic Additions

Regioselective reactions of 3; 4-pyridynes enabled by the aryne distortion model

安全性情報

• ピクトグラム: GHS07
• シグナルワード: Warning
• 危険有害性情報: H315,H319,H335
• 注意書き: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• 危険有害性の分類: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• ターゲットの組織: Respiratory system
• 保管分類コード: 11 - Combustible Solids
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable