8.22340

Phosphorus pentachloride

for synthesis

• 別名: Phosphorus pentachloride, Phosphorus(V) chloride
• 実験式（ヒル表記法）: Cl₅P
• CAS番号: 10026-13-8
• 分子量: 208.24
• MDL番号: MFCD00011439
• UNSPSCコード: 12352307
• EC Index Number: 233-060-3
• NACRES: NA.22

特性

• 蒸気圧: 0.016 hPa ( 20 °C)
• 品質水準: 200
• アッセイ: ≥99.0% (argenometric)
• 形状: crystalline solid
• 有効性: 660 mg/kg LD₅₀, oral (Rat)
• pH: 1 (5 g/L in H₂O, acidic)
• mp: 148 °C
• 密度: 2.1 g/cm³ at 20 °C
• 保管温度: 2-30°C
• InChI: 1S/Cl5P/c1-6(2,3,4)5
• InChI Key: UHZYTMXLRWXGPK-UHFFFAOYSA-N

詳細

アプリケーション

• Phosphorylation of Glycoluryl Derivatives: New organoelement phosphorus derivatives synthesized using glycoluril and phosphorus pentachloride under controlled conditions (Salkeeva et al., 2021).


• Alcohol Amination and Cyclization: Catalyzed alcohol amination of diethanolamine by a Ru-PNP Pincer complex using phosphorus pentachloride to produce piperazine, demonstrating high conversion rates (van der Loo et al.).


• Chemical Weapons Convention Relevance: Rapid GC-MS screening of chlorides relevant to the Chemical Weapons Convention, including phosphorus pentachloride, for monitoring prohibited chemical activities (Kuitunen et al., 2020).


• Silicon Nanocrystal Functionalization: Phosphorus pentachloride used for the functionalization of silicon nanocrystals, enhancing their utility in advanced materials applications (Islam et al., 2017).

アナリシスノート

Assay (argentometric): ≥ 99.0 %

安全性情報

• ピクトグラム: GHS05,GHS06,GHS08
• シグナルワード: Danger
• 危険有害性情報: H302 - H314 - H330 - H373
• 注意書き: P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P314
• 危険有害性の分類: Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B - STOT RE 2 Inhalation
• ターゲットの組織: Respiratory Tract
• 補足的ハザード: EUH014 - EUH029
• 保管分類コード: 6.1B - Non-combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
• WGK: WGK 1