83374

水銀(II)チオシアナート

purum p.a., ≥95.5% (complexometric)

• 別名: チオシアン酸, 水銀(II)塩, チオシアン酸第二水銀, 水銀 ジ(チオシアナート), 第二水銀 イソチオシアナート, 第二水銀 スルホシアニド
• 化学式: Hg(SCN)₂
• CAS番号: 592-85-8
• 分子量: 316.75
• Beilstein: 3561344
• EC Number: 209-773-0
• MDL番号: MFCD00011039
• UNSPSCコード: 12161600
• PubChem Substance ID: 329769071
• NACRES: NA.22

特性

• グレード: purum p.a.
• 品質水準: 100
• アッセイ: ≥95.5% (complexometric)
• フォーム: solid
• 反応適合性: core: mercury; reagent type: catalyst
• mp: 165 °C (dec.) (lit.)
• 密度: 3.71 g/mL at 25 °C (lit.)
• 微量陽イオン: Ca: ≤50 mg/kg; Cd: ≤50 mg/kg; Co: ≤50 mg/kg; Cu: ≤50 mg/kg; Fe: ≤50 mg/kg; K: ≤1000 mg/kg; Na: ≤100 mg/kg; Ni: ≤50 mg/kg; Pb: ≤50 mg/kg; Zn: ≤50 mg/kg
• SMILES記法: N#CS[Hg]SC#N
• InChI: 1S/2CHNS.Hg/c2*2-1-3;/h2*3H;/q;;+2/p-2
• InChI Key: GBZANUMDJPCQHY-UHFFFAOYSA-L

詳細

アプリケーション

Catalyst for addition of HSCN to alkynes.

Mercury(II) thiocyanate has been used for the determination of the chloride ions by colorimetric method.
It can be employed as a reactant for the synthesis of:

• Polymeric mercury(II) coordination complexes with various derivatives of 4,4′-bipyridine ligands via the branched tube method.
• Manganese mercury thiocyanate (MMTC), an organometallic optical single-crystal.
• Heterotrinuclear copper(II)–mercury(II)–copper(II) complexes possessing antibacterial and antifungal activities.

免責事項

For U.S. Customers: Contains mercury; Do not place in trash - dispose according to local, state, or federal laws.

安全性情報

• ピクトグラム: GHS06,GHS08,GHS09
• シグナルワード: Danger
• 危険有害性情報: H300 + H310 + H330,H373,H410
• 注意書き: P262 - P264 - P273 - P280 - P302 + P352 + P310 - P304 + P340 + P310
• 危険有害性の分類: Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2
• 補足的ハザード: EUH032
• 保管分類コード: 6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
• WGK: WGK 3
• 引火点(°F): 248.0 °F - closed cup
• 引火点(℃): 120 °C - closed cup
• 個人用保護具 (PPE): Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges