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Merck
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문서

D161608

Sigma-Aldrich

N,N-Dimethylhydrazine

98%

동의어(들):

1,1-Dimethylhydrazine, asym-Dimethylhydrazine

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About This Item

Linear Formula:
(CH3)2NNH2
CAS Number:
57-14-7
Molecular Weight:
60.10
Beilstein:
605261
EC Number:
200-316-0
MDL number:
MFCD00007628
UNSPSC 코드:
12352100
PubChem Substance ID:
24893497
NACRES:
NA.22

vapor density

1.94 (vs air)

vapor pressure

103 mmHg ( 20 °C)

분석

98%

형태

liquid

autoignition temp.

478 °F

expl. lim.

95 %

refractive index

n20/D 1.4075 (lit.)

bp

60-62 °C (lit.)

density

0.79 g/mL at 20 °C (lit.)

저장 온도

2-8°C

SMILES string

CN(C)N

InChI

1S/C2H8N2/c1-4(2)3/h3H2,1-2H3

InChI key

RHUYHJGZWVXEHW-UHFFFAOYSA-N

유사한 제품을 찾으십니까? 방문 제품 비교 안내

애플리케이션

N,N-Dimethylhydrazine can react with:
  • β-Naphthol via radical amination to form 1-amino-2-naphthol.
  • 2-Chloro- and 2,2-dichloro-(bromo)vinyl ketones via regioselective heterocyclization to form 3-substituted 1-methyl(5-halo)pyrazoles.
  • Terminal alkynes in the presence of TpRuCl(PPh3)2 (Tp = tris(pyrazolyl)borate) to form nitriles.


N,N-Dimethylhydrazine along with ferric chloride hexahydrate forms an effective reduction system for:
  • Synthesizing DNA binding pyrrolo[2,1-c][1,4]benzodiazepine (PBD) imines via reductive cyclization of the corresponding nitro aldehyde.
  • Transforming a variety of nitroarenes and azido compounds into the corresponding anilines and amino compounds, respectively.

생화학적/생리학적 작용

Lung and colon tumor initiator in experimental animal model.

신호어

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 2 - Carc. 1B - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

표적 기관

Respiratory system

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point (°F)

14.0 °F - closed cup

Flash Point (°C)

-10 °C - closed cup

개인 보호 장비

Faceshields, Gloves, Goggles

시험 성적서(COA)

제품의 로트/배치 번호를 입력하여 시험 성적서(COA)을 검색하십시오. 로트 및 배치 번호는 제품 라벨에 있는 ‘로트’ 또는 ‘배치’라는 용어 뒤에서 찾을 수 있습니다.

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문서 라이브러리 방문

이미 열람한 고객

Slide 1 of 1

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1,2-Diacetylhydrazine 98%

Sigma-Aldrich

D8402

1,2-Diacetylhydrazine

Masaki Honda et al.
Marine drugs, 17(2) (2019-02-06)
The red macroalga Agarophyton chilensis is a well-known producer of eicosanoids such as hydroxyeicosatetraenoic acids, but the alga produces almost no prostaglandins, unlike the closely related A. vermiculophyllum. This indicates that the related two algae would have different enzyme systems
Reaction of terminal alkynes with hydrazines to give nitriles, catalyzed by TpRuCl (PPh3)2: novel catalytic transformation involving a vinylidene ruthenium intermediate
Fukumoto Y, et al.
Organometallics, 21(19), 3845-3847 (2002)
An efficient synthesis of pyrrolo [2, 1-c][1, 4] benzodiazepine antibiotics via reductive cyclization
Kamal A, et al.
Bioorganic & Medicinal Chemistry Letters, 7(14), 1825-1828 (1997)
A mild and efficient method for the preparation of anilines from nitroarenes
Boothroyd SR and Kerr MA
Tetrahedron Letters, 36(14), 2411-2414 (1995)
On the reaction of β-naphthol with N, N-dimethylhydrazine-a new radical amination process
Barton DHR, et al.
Tetrahedron Letters, 24(15), 1601-1604 (1983)
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