144819

1-(Trimethylsiloxy)cyclohexene

99%

• 別名: 1-Cyclohexenyloxytrimethylsilane, Cyclohexanone enol trimethylsilyl ether
• 化学式: C₆H₉OSi(CH₃)₃
• CAS番号: 6651-36-1
• 分子量: 170.32
• Beilstein: 1859394
• EC Number: 229-675-1
• MDL番号: MFCD00001541
• UNSPSCコード: 12352100
• PubChem Substance ID: 24848686
• NACRES: NA.22

特性

• アッセイ: 99%
• 形状: liquid
• 屈折率: n20/D 1.447 (lit.)
• bp: 64-65 °C/15 mmHg (lit.)
• 密度: 0.875 g/mL at 25 °C (lit.)
• SMILES記法: C[Si](C)(C)OC1=CCCCC1
• InChI: 1S/C9H18OSi/c1-11(2,3)10-9-7-5-4-6-8-9/h7H,4-6,8H2,1-3H3
• InChI Key: SBEMOANGDSSPJY-UHFFFAOYSA-N

詳細

詳細

1-(Trimethylsiloxy)cyclohexene undergoes Michael addition reaction with methyl vinyl ketone in the presence of dibutyltin bis(triflate).

アプリケーション

1-(Trimethylsiloxy)cyclohexene was used in one-pot synthesis of Δ^1,9- octalone. It is intermediate to many complex compounds including natural products.

安全性情報

• ピクトグラム: GHS02
• シグナルワード: Warning
• 危険有害性情報: H226
• 危険有害性の分類: Flam. Liq. 3
• 保管分類コード: 3 - Flammable liquids
• WGK: WGK 3
• 引火点(°F): 105.8 °F - closed cup
• 引火点(℃): 41 °C - closed cup
• 個人用保護具 (PPE): Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter