218847

三フッ化ホウ素メチルエーテラート

• 別名: (Dimethyl ether)trifluoroboron
• 化学式: BF₃ · O(CH₃)₂
• CAS番号: 353-42-4
• 分子量: 113.87
• Beilstein: 3613739
• EC Number: 206-532-1
• MDL番号: MFCD00013192
• UNSPSCコード: 12352106
• PubChem Substance ID: 24853093
• NACRES: NA.22

特性

• フォーム: liquid
• 品質水準: 100
• 自己発火温度: 455 °F
• expl. lim.: 21.6 %
• 反応適合性: core: boron; reagent type: Lewis acid; reagent type: catalyst
• 屈折率: n20/D 1.308 (lit.)
• bp: 126-127 °C (lit.)
• mp: −15 °C (lit.)
• 密度: 1.239 g/mL at 25 °C (lit.)
• 官能基: ether
• SMILES記法: C[O+](C)[B-](F)(F)F
• InChI: 1S/C2H6BF3O/c1-7(2)3(4,5)6/h1-2H3
• InChI Key: FOWZWMGLMYVYDH-UHFFFAOYSA-N

詳細

アプリケーション

Reactant or reagent involved in:

• Deconvoluting the chemical reaction kinetics of platinum-silver ligand exchange
• Synthesis of neurogenic ganglioside LLG-3 from starfish via glycosylation reactions
• Synthesis of peloruside via lactonization and relay ring-closing metathesis cyclization
• FRET for monitoring Pd-catalyzed nucleophilic allylic substitution reactions
• Single molecuel imaging of fluorophore-tagged palldium(II) complexes
• β-elimination and rearrangement reactions for synthesis of exocyclic vinyl ethers

安全性情報

• ピクトグラム: GHS02,GHS08,GHS05,GHS07
• シグナルワード: Danger
• 危険有害性情報: H260,H302 + H332,H314,H335,H373
• 注意書き: P231 + P232 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P314
• 危険有害性の分類: Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1A - STOT RE 2 Inhalation - STOT SE 3 - Water-react 1
• ターゲットの組織: Kidney, Respiratory system
• 保管分類コード: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• WGK: WGK 3
• 引火点(°F): 143.6 °F - closed cup
• 引火点(℃): 62 °C - closed cup
• 個人用保護具 (PPE): Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter