28115

クロチルクロリド

technical, (cis+trans), mixture of cis- and trans-isomers (~1:6), ~70% (GC)

• 別名: cis,trans-1-クロロ-2-ブテン
• 化学式: CH₃CH=CHCH₂Cl
• CAS番号: 591-97-9
• 分子量: 90.55
• Beilstein: 605304
• EC Number: 209-739-5
• MDL番号: MFCD00000987
• UNSPSCコード: 12352100
• PubChem Substance ID: 57648288
• NACRES: NA.22

特性

• 品質水準: 100
• グレード: technical
• アッセイ: ~70% (GC)
• フォーム: liquid
• 不純物: ~30% 3-chloro-1-butene
• 屈折率: n20/D 1.430
• bp: 85-86 °C (lit.)
• 溶解性: water: soluble 14 g/L at 20 °C
• 密度: 0.923 g/mL at 20 °C (lit.)
• 官能基: alkyl halide; chloro
• SMILES記法: C\C=C\CCl
• InChI: 1S/C4H7Cl/c1-2-3-4-5/h2-3H,4H2,1H3/b3-2+
• InChI Key: YTKRILODNOEEPX-NSCUHMNNSA-N

詳細

詳細

Crotyl chloride reacts with trichlorosilane in the presence of tertiary amine and copper salts to give the corresponding allyltrichlorosilanes.

アプリケーション

Crotyl chloride has been used:

• to investihgate the kinetics of the reactions of atomic chlorine with series of unsaturated aldehydes and ketones at 298K, to probe structure-reactivity relationships
• in the preparation of (E)-crotyltrichlorosilane

安全性情報

• ピクトグラム: GHS02,GHS06,GHS05
• シグナルワード: Danger
• 危険有害性情報: H225,H301,H314,H317,H412
• 注意書き: P210 - P273 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• 危険有害性の分類: Acute Tox. 3 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - Skin Sens. 1
• 保管分類コード: 3 - Flammable liquids
• WGK: WGK 3
• 引火点(°F): 10.4 °F - closed cup
• 引火点(℃): -12 °C - closed cup
• 個人用保護具 (PPE): Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter