791806

Yu-Wasa Auxiliary

97%

• 別名: 2,3,5,6-Tetrafluoro-4-(trifluoromethyl)aniline, 2,3,5,6,α,α,α-Heptafluoro-p-toluidine
• 化学式: CF₃C₆F₄NH₂
• CAS番号: 651-83-2
• 分子量: 233.09
• Beilstein: 2657893
• MDL番号: MFCD00091518
• UNSPSCコード: 12352101
• PubChem Substance ID: 329768293
• NACRES: NA.22

特性

• 品質水準: 100
• アッセイ: 97%
• 形状: liquid
• 反応適合性: reaction type: C-C Bond Formation; reagent type: catalyst; reaction type: C-H Activation
• 屈折率: n20/D 1.431 (lit.); n20/D 1.432
• bp: 186 °C (lit.)
• 密度: 1.662 g/mL at 25 °C; 1.687 g/mL at 25 °C (lit.)
• 官能基: fluoro
• SMILES記法: Nc1c(F)c(F)c(c(F)c1F)C(F)(F)F
• InChI: 1S/C7H2F7N/c8-2-1(7(12,13)14)3(9)5(11)6(15)4(2)10/h15H2
• InChI Key: FJOACTZFMHZHSC-UHFFFAOYSA-N

詳細

その他情報

Acidic amides are superior directing groups for promoting C-H activation reactions with both Pd(0)/PR₃ and Pd(II) catalysts.

Used in the Preparation of

• Lactams via palladium-catalyzed olefination of arylamides with benzylacrylate, followed by 1,4-conjugate addition
• N-(fluorinated aryl)benzamides as substrates for regioselective C-H amination reactions with O-benzoylhydroxylamines
• Substituted succinimides via palladium-catalyzed carbonylation of N-aryl amides
• N-aryl cyclopropanecarboxamide substrates and various amino acid ligands for palladium-catalyzed C-H activation of cyclopropanes

安全性情報

• ピクトグラム: GHS07
• シグナルワード: Warning
• 危険有害性情報: H315,H319,H335
• 注意書き: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• 危険有害性の分類: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• ターゲットの組織: Respiratory system
• 保管分類コード: 10 - Combustible liquids
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable