81900

プロピオニトリル

purum, ≥99.0% (GC)

• 別名: シアン化エチル
• 化学式: CH₃CH₂CN
• CAS番号: 107-12-0
• 分子量: 55.08
• Beilstein: 773680
• EC Number: 203-464-4
• MDL番号: MFCD00001948
• UNSPSCコード: 12352100
• PubChem Substance ID: 329769223
• NACRES: NA.22

特性

• グレード: purum
• 品質水準: 200
• アッセイ: ≥99.0% (GC)
• 形状: liquid
• 屈折率: n20/D 1.366 (lit.); n20/D 1.366
• bp: 97 °C (lit.)
• mp: −93 °C (lit.)
• 密度: 0.772 g/mL at 25 °C (lit.)
• 官能基: nitrile
• SMILES記法: CCC#N
• InChI: 1S/C3H5N/c1-2-3-4/h2H2,1H3
• InChI Key: FVSKHRXBFJPNKK-UHFFFAOYSA-N

詳細

アプリケーション

• Propionitrile (PPN) is an effective solvent for catalytic asymmetric aldol reaction of a silyl enol ether with aldehydes in the presence of a chiral tin(II) Lewis acid catalyst.
• The co-solvent formed by mixing PPN with acetonitrile can be used to fabricate polymer gel electrolytes (PGEs) of dye-sensitized solar cells (DSSCs), which lead to enhanced stability of gel-state DSSCs.
• PPN can be used as a solvent for the Brønsted acid-catalyzed synthesis of N-alkyl cis-aziridines via [2+1] annulation of a diazo compound formed by the combination of an acetate and enolate. The process does not involve the use of metals or reagents and only atomic nitrogen as a co-product.

安全性情報

• ピクトグラム: GHS02,GHS06
• シグナルワード: Danger
• 危険有害性情報: H225,H300 + H310,H319,H332
• 注意書き: P210 - P280 - P301 + P310 - P303 + P361 + P353 - P304 + P340 + P312 - P305 + P351 + P338
• 危険有害性の分類: Acute Tox. 2 Dermal - Acute Tox. 2 Oral - Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 2
• 保管分類コード: 3 - Flammable liquids
• WGK: WGK 1
• 引火点(°F): 42.8 °F - closed cup
• 引火点(℃): 6 °C - closed cup
• 個人用保護具 (PPE): Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter