414670

1-ヨード-2-(トリメチルシリル)アセチレン

97%

• 化学式: (CH₃)₃SiC≡CI
• CAS番号: 18163-47-8
• 分子量: 224.11
• MDL番号: MFCD00274201
• UNSPSCコード: 12352100
• PubChem Substance ID: 24865951
• NACRES: NA.22

特性

• 品質水準: 100
• アッセイ: 97%
• 形状: liquid
• 屈折率: n20/D 1.511 (lit.)
• bp: 130 °C (lit.)
• 密度: 1.46 g/mL at 25 °C (lit.)
• 官能基: iodo
• 保管温度: 2-8°C
• SMILES記法: C[Si](C)(C)C#CI
• InChI: 1S/C5H9ISi/c1-7(2,3)5-4-6/h1-3H3
• InChI Key: HNIRHTRSZDSMOF-UHFFFAOYSA-N

詳細

アプリケーション

1-Iodo-2-(trimethylsilyl)acetylene may be used to investigate the reactivity of diamagnetic cobalt(I) complex, Tol-BDI((2-pp)₂)Co [Tol-BDI((2-pp)₂)H = 2-(4-tolyl)-1,3-bis(2-isopropylpyridyl)propenediimine]. It may be used for the synthesis of 1-(4-trimethylsilanylbuta-1,3-diynyl)pyrene, via Pd-coupling with 1-iodo-2-trimethylsilylacetylene.

安全性情報

• ピクトグラム: GHS02,GHS08,GHS07
• シグナルワード: Danger
• 危険有害性情報: H226,H302 + H312 + H332,H317,H334,H361
• 注意書き: P202 - P210 - P280 - P301 + P312 - P303 + P361 + P353 - P308 + P313
• 危険有害性の分類: Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Flam. Liq. 3 - Repr. 2 - Resp. Sens. 1 - Skin Sens. 1
• 保管分類コード: 3 - Flammable liquids
• WGK: WGK 3
• 引火点(°F): 118.4 °F - closed cup
• 引火点(℃): 48 °C - closed cup
• 個人用保護具 (PPE): Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter