469785

ベンジルグリシジルエーテル

99%

• 別名: (Benzyloxymethyl)oxirane, (±)-O-Benzylglycidol, 1-(Benzyloxy)-2,3-epoxypropane, 2-[(Phenylmethoxy)methyl]oxirane, 2-[[(Benzyloxy)methyl]oxy]oxirane, 3-(Benzyloxy)-1,2-epoxypropane, Glycidyl benzyl ether, [(Phenylmethoxy)methyl]oxirane
• 実験式（ヒル表記法）: C₁₀H₁₂O₂
• CAS番号: 2930-05-4
• 分子量: 164.20
• EC Number: 220-899-5
• MDL番号: MFCD00068664
• UNSPSCコード: 12352100
• PubChem Substance ID: 24870484
• NACRES: NA.22

特性

• 品質水準: 100
• アッセイ: 99%
• 屈折率: n20/D 1.5170 (lit.)
• bp: 70-73 °C/11 mmHg (lit.)
• 密度: 1.077 g/mL at 25 °C (lit.)
• 官能基: ether; phenyl
• 保管温度: 2-8°C
• SMILES記法: C(OCc1ccccc1)C2CO2
• InChI: 1S/C10H12O2/c1-2-4-9(5-3-1)6-11-7-10-8-12-10/h1-5,10H,6-8H2
• InChI Key: QNYBOILAKBSWFG-UHFFFAOYSA-N

詳細

詳細

Benzyl glycidyl ether is a glycidyl derivative. Rac-/(R)-benzyl glycidyl ether participates in the synthesis of atactic and isotactic linear poly(benzyl 1,2-glycerol carbonate)s. Biocatalytic resolution of racemic benzyl glycidyl ether by Talaromyces flavus has been described. Resolution of benzyl glycidyl ether to (S)-benzyl glycidyl ether with 30% ee and (R)-3-benzyloxypropane-1,2-diol with 40% ee by whole Bacillus alcalophilus cells has been reported. It reacts with K^-, K⁺(15-crown-5)₂ to afford potassium glycidoxide and bibenzyl.

安全性情報

• ピクトグラム: GHS07
• シグナルワード: Warning
• 危険有害性情報: H315,H319,H335
• 注意書き: P302 + P352 - P305 + P351 + P338
• 危険有害性の分類: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• ターゲットの組織: Respiratory system
• 保管分類コード: 10 - Combustible liquids
• WGK: WGK 3
• 引火点(°F): 235.4 °F - closed cup
• 引火点(℃): 113 °C - closed cup
• 個人用保護具 (PPE): Eyeshields, Gloves, type ABEK (EN14387) respirator filter