526134

tert-Butyldimethylsilyl glycidyl ether

98%

• 実験式（ヒル表記法）: C₉H₂₀O₂Si
• CAS番号: 78906-15-7
• 分子量: 188.34
• MDL番号: MFCD02683555
• UNSPSCコード: 12352100
• PubChem Substance ID: 24874536
• NACRES: NA.22

特性

• アッセイ: 98%
• 屈折率: n20/D 1.531 (lit.)
• bp: 195-197 °C (lit.)
• 密度: 0.901 g/mL at 25 °C (lit.)
• 官能基: ether
• SMILES記法: CC(C)(C)[Si](C)(C)OCC1CO1
• InChI: 1S/C9H20O2Si/c1-9(2,3)12(4,5)11-7-8-6-10-8/h8H,6-7H2,1-5H3
• InChI Key: YANSSVVGZPNSKD-UHFFFAOYSA-N

詳細

詳細

tert-Butyldimethylsilyl glycidyl ether [tert-butyl-dimethyl-(oxiran-2-ylmethoxy)silane] can be synthesized from glycidol, via hydrolytic kinetic resolution (HKR) in the presence of R-(salen)Co complex and water.

アプリケーション

tert-Butyldimethylsilyl glycidyl ether may be used to synthesize (R/S)-1-benzylamino-3-(tert-butyldimethylsilyloxy)propan-2-ol and (2R/2S)-1-(tert-butyldimethylsilyloxy)-3-{[(4S)-2,2-dimethyl-1,3-dioxolan-4-ylmethyl]amino}propan-2-ol.

安全性情報

• 保管分類コード: 10 - Combustible liquids
• WGK: WGK 3
• 引火点(°F): 158.0 °F - closed cup
• 引火点(℃): 70 °C - closed cup
• 個人用保護具 (PPE): Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)