680990

1,1'-ビス[(2R,5R)-2,5-ジメチルホスホラノ]フェロセン

• 別名: R,R-Et-Ferrocelane^™
• 実験式（ヒル表記法）: C₂₆H₄₀FeP₂
• CAS番号: 147762-89-8
• 分子量: 470.39
• UNSPSCコード: 12352005
• PubChem Substance ID: 24885607
• NACRES: NA.22

特性

• 形状: solid
• 品質水準: 100
• 光学活性: [α]20/D +380°, c = 1 in chloroform
• mp: 85-91 °C
• 官能基: phosphine
• SMILES記法: C[Fe]C.CC[C@@H]1CC[C@@H](CC)P1[C@@H]2CCCC2.CC[C@@H]3CC[C@@H](CC)P3[C@H]4CCCC4
• InChI: 1S/2C13H25P.2CH3.Fe/c2*1-3-11-9-10-12(4-2)14(11)13-7-5-6-8-13;;;/h2*11-13H,3-10H2,1-2H3;2*1H3;/t2*11-,12-;;;/m11.../s1
• InChI Key: CPUKIDAUDCWIRT-QULUYMGFSA-N

詳細

アプリケーション

DuPhos and BPE Ligands: Highly Efficient Privileged Ligands

1,1′-Bis[(2R,5R)-2,5-diethylphospholano]ferrocene can be used:

• As a catalyst in the asymmetric hydrogenation reactions of olefins and ketones.
• As a component of a rhodium based precatalyst, applicable in the 2-methylenesuccinamic acid hydrogenation reaction.

法的情報

Sold in collaboration with Kanata Chemical Technologies Inc. for research purposes only. These compounds were made and sold under license from E.I. du Pont de Nemours and Company, which license does not include the right to use the compounds in producing products for sale in the pharmaceutical field.

Ferrocelane is a trademark of Kanata Chemical Technologies, Inc.

安全性情報

• 保管分類コード: 11 - Combustible Solids
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable