928305

cataCXium^® A Pd G3 ChemBeads

• 別名: Mesylate[(di(1-adamantyl)-n-butylphosphine)-2-(2′-amino-1,1′-biphenyl)]palladium(II), [(Di(1-adamantyl)-butylphosphine)-2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate, cataCXium-A-Pd-G3
• 実験式（ヒル表記法）: C₃₇H₅₂NO₃PPdS
• CAS番号: 1651823-59-4
• 分子量: 728.27
• MDL番号: MFCD28144563
• UNSPSCコード: 12352101
• NACRES: NA.82

特性

• フォーム: solid
• 品質水準: 100
• 組成: ~ 4 wt.% loading of catalyst
• 反応適合性: reagent type: catalyst; reaction type: Cross Couplings
• SMILES記法: [Pd+2].P(C76CC8CC(C7)CC(C6)C8)(C43CC5CC(C4)CC(C3)C5)CCCC.[S](=O)(=O)([O-])C.Nc1c(cccc1)c2[c-]cccc2

詳細

アプリケーション

cataCXium^® A Pd G3 is a Buchwald third generation precatalyst that can be used in:

• Direct ortho-arylation of pyridinecarboxylic acids.
• Catalyzing Suzuki–Miyaura cross-coupling in the synthesis of 1-heteroaryl-3-azabicyclo[3.1.0]hexanes.
• Palladium-catalyzed carbonylative carboperfluoroalkylation of alkynes.
• Suzuki–Miyaura coupling reaction of geminal bis(boryl)cyclopropanes in the synthesis of various gem-disubstituted cyclopropanes.

ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.

Learn more about ChemBeads products

For larger scale uses, product also available in powdered form (761435)

その他情報

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Versatile Methods to Dispense Sub-Milligram Quantities of Solids using Chemical Coated Beads for High-Throughput Experimentation

ChemBead Enabled High-Throughput Cross-Electrophile Coupling Reveals a New Complementary Ligand

法的情報

cataCXium is a registered trademark of Umicore AG & Co. KG

安全性情報

• ピクトグラム: GHS08
• シグナルワード: Danger
• 危険有害性情報: H350i
• 注意書き: P201 - P202 - P280 - P308 + P313 - P405 - P501
• 危険有害性の分類: Carc. 1B Inhalation
• 保管分類コード: 6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
• WGK: WGK 3