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GC Analysis of 1-Phenylethanol Enantiomers on Astecยฎ CHIRALDEXโ„ข B-PM

GC Analysis of 1-Phenylethanol Enantiomers on Astec® CHIRALDEX™ B-PM suitable for GC

Materials

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Astecยฎ CHIRALDEXโ„ข B-PM Capillary GC Column

L ร— I.D. 30 m ร— 0.25 mm, df 0.12 ฮผm

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(R)-(+)-1-Phenylethanol

for chiral derivatization, LiChropurโ„ข, โ‰ฅ99.0%

1-Phenylethanol-2,2,2-d3

98 atom % D

1-Phenylethanol-1,2-13C2

99 atom % 13C

1-Phenylethanol

98%

1-Phenyl-d5-ethanol

98 atom % D

(S)-(โˆ’)-1-Phenylethanol

≥98.5% (sum of enantiomers, GC)

(R)-(+)-1-Phenylethanol

≥98.5% (sum of enantiomers, GC)

1-Phenylethan-1,2,2,2-d4-ol

98 atom % D

1-Phenylethanol-d10

98 atom % D

1-Phenylethanol-1-13C

99 atom % 13C

1-Phenylethanol-2-13C

99 atom % 13C, 99% (CP)

1-Phenyl-1-ethanol

5000 μg/mL in ethanol: isopropanol (95:5), analytical standard

(S)-(โˆ’)-1-Phenylethanol

97%

(R)-1-Phenylethanol

97%

CONDITIONS

column

Astec CHIRALDEX B-PM, 30 m x 0.25 mm I.D., 0.12 μm (76023AST)

oven

120 ยฐC

inj. temp.

250 ยฐC

detector

FID, 250 ยฐC

carrier gas

helium, 24 psi

injection

1 μL, 80:1 split

sample

3 mg/mL in methanol
peak 1: R(+)-1-phenylethanol
peak 2: S(-)-1-phenylethanol

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Astec is a registered trademark of Merck KGaA, Darmstadt, Germany
CHIRALDEX is a trademark of Sigma-Aldrich Co. LLC