406341

臭化ニッケル(II)エチレングリコールジメチルエーテル錯体

97%

• 別名: ジブロモ（1,2-ジメトキシエタン）ニッケル, ジブロモ（1,2-ジメトキシエタン）ニッケル（II）, （1,2-ジメトキシエタン）二臭化ニッケル
• 化学式: NiBr₂ · CH₃OCH₂CH₂OCH₃
• CAS番号: 28923-39-9
• 分子量: 308.62
• MDL番号: MFCD00013480
• UNSPSCコード: 12352302
• PubChem Substance ID: 24865368
• NACRES: NA.23

特性

• 品質水準: 100
• アッセイ: 97%
• 形状: powder
• 反応適合性: reagent type: catalyst; core: nickel
• SMILES記法: Br[Ni]Br.COCCOC
• InChI: 1S/C4H10O2.2BrH.Ni/c1-5-3-4-6-2;;;/h3-4H2,1-2H3;2*1H;/q;;;+2/p-2
• InChI Key: VHSVJTYBTJCDFL-UHFFFAOYSA-L

詳細

詳細

Nickel(II) bromide ethylene glycol dimethyl ether complex, also known as Ni(II) bromide ethylene glycol dimethyl ether complex. It is an organometallic coordination compound used as a precursor for the deposition of nickel-containing thin films. It is also found applications in organic synthesis as a Lewis acid catalyst.

アプリケーション

Nickel(II) bromide ethylene glycol dimethyl ether complex can be used as a precursor for synthesizing various nickel(II) complexes. These complexes used as a catalysts for:      

• The selective transformation of ethylene into higher-order products.     
• The vinyl polymerization of norbornene.      
• The preparation of poly(3-hexylthiophene) (P3HT) Kumada catalyst transfer polymerization. It facilitates good control over the molecular weight of the conjugating polymer.

安全性情報

• ピクトグラム: GHS02,GHS08,GHS07,GHS09
• シグナルワード: Danger
• 危険有害性情報: H228,H317,H332,H334,H341,H351,H361f,H372,H410
• 注意書き: P202 - P210 - P273 - P280 - P302 + P352 - P308 + P313
• 危険有害性の分類: Acute Tox. 4 Inhalation - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 Inhalation - Flam. Sol. 1 - Muta. 2 - Repr. 2 - Resp. Sens. 1 - Skin Sens. 1 - STOT RE 1 Inhalation
• ターゲットの組織: Respiratory Tract,Skin
• 保管分類コード: 4.1B - Flammable solid hazardous materials
• WGK: WGK 3
• 引火点(°F): 26.6 °F - Non-equilibrium method
• 引火点(℃): -3 °C - Non-equilibrium method
• 個人用保護具 (PPE): dust mask type N95 (US), Eyeshields, Gloves, type P3 (EN 143) respirator cartridges